As described in the Deposition section, in capacitively coupled reactors (CCP) the same voltage determines both ion density and ion energy – the two cannot be set independently. Inductively coupled reactors (ICP) separate these two quantities using a separate bias voltage at the wafer electrode.
This separation matters especially for etching: a high etch rate needs many reactive species, i.e. a high ion density, while a clean anisotropic profile needs controlled, not too high, ion energy. The construction differs accordingly: CCP reactors often use silicon or SiC electrodes as consumable material to avoid metal contamination of the wafer; the chamber walls are usually anodized aluminum, which must withstand the aggressive fluorine and chlorine radicals. In ICP reactors, the coil sits outside a dielectric chamber window made of quartz or ceramic, through which the alternating field can penetrate.
The achievable ion density with ICP is typically 10 to 100 times higher than with CCP – the main reason why ICP is the standard today for demanding etch processes with high aspect ratios.