1. From LED to Laser: Population Inversion and Stimulated Emission
The fundamental difference between an LED and a laser diode lies not in the basic structure – both are based on a pn junction made from a direct-bandgap semiconductor – but in the emission mechanism. An LED generates light through spontaneous emission: an excited electron recombines with a hole at a random point in time, and the resulting photon has a random phase and direction. A laser, by contrast, relies on stimulated emission: a photon that already exists strikes an excited electron-hole pair and triggers its recombination – the newly generated photon is then identical in phase, direction, and wavelength to the triggering photon. This amplification mechanism (Light Amplification by Stimulated Emission of Radiation) produces coherent light, in contrast to the incoherent light of an LED.
For stimulated emission to dominate over absorption, the active medium must exhibit population inversion: more electrons must occupy the higher-energy conduction band state than the lower valence band state – a condition that never occurs in thermal equilibrium and must therefore be actively forced through high injection current density. In semiconductor lasers, the strongly forward-biased pn junction performs this role: above a certain threshold current, the ratio flips, optical gain sets in, and spontaneous emission increasingly gives way to stimulated emission.