1. Why Indium Phosphide for Photonics
Indium phosphide (InP) has a direct band gap of about 1.35 eV, corresponding to a cutoff wavelength of around 920 nm, making it directly suitable for light generation and detection, unlike silicon, whose indirect band gap prevents efficient light emission. By combining InP with the ternary and quaternary compounds InGaAs (band gap of the lattice-matched composition In0.53Ga0.47As about 0.75 eV) and InGaAsP, which can be grown lattice-matched to the InP lattice constant of 5.869 Å, the band gap and therefore the emission or absorption wavelength can be tuned over a wide range of roughly 0.92 to 1.65 µm.
Of particular importance is coverage of the two central telecommunication windows at 1.3 µm (minimum chromatic dispersion in standard single-mode fiber) and 1.55 µm (minimum attenuation of about 0.2 dB/km in optical fiber). The lattice match between InP and the quaternary InGaAsP layers, with a mismatch well under 0.1 %, ensures that the epitaxial layers grow nearly defect-free, which is critical for device lifetime.