1. Electromigration
Electromigration refers to the transport of material within a metal conductor caused by the momentum transfer from drifting conduction electrons to the metal ions of the crystal lattice, often called the electron wind. At the high current densities of modern interconnect levels, on the order of several MA/cm², metal atoms preferentially migrate along grain boundaries in the direction of current flow. Material accumulates on the anode side, forming hillocks, while vacancies coalesce into voids on the cathode side, which can narrow the conductor cross-section until it fails completely.
The mean time to failure of an interconnect due to electromigration is described by the empirical Black equation MTTF = A · J-n · eEa/(k·T), where J is the current density, T the temperature, Ea the activation energy, k the Boltzmann constant, and the current density exponent n is typically close to 2. For aluminum interconnect, the allowable design current density is usually in the range of 1 to 2 MA/cm² with an activation energy of about 0.5 to 0.7 eV along grain boundaries; copper, with an activation energy of roughly 0.7 to 1.1 eV and lower self-diffusion, achieves a much higher electromigration resistance at the same current density. This improvement was one of the key drivers behind the introduction of copper interconnect technology in the 1990s, since it was what first made higher current densities reliably possible as wire cross-sections continued to shrink.